A HgTe/ZnO Quantum Dots Vertically Stacked Heterojunction Low dark current Photodetector
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1.Shanghai Institute of Technical Physics Chinese Academy of Sciences;2.Kunming Institute of Physics;3.Frontier Institute of Chip and System, Fudan University

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National key research and development program in the 14th five year plan (Grant No. 2021YFA1200700 (J.W.)), National Natural Science Foundation of China (Grant Nos. 62104235 (J.L.), 62105348 (T.G.), 62025405 (J.W.)), Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB44000000 (J.W.)), Shanghai Pujiang Program (Grant No. 21PJ1414900 (T.G.)).

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    Abstract:

    Colloidal quantum dots (CQDs) are affected by the quantum confinement effect, which makes their bandgap tunable. This characteristic allows these materials to cover a broader infrared spectrum, providing a cost-effective alternative to traditional infrared detector technology. Recently, thanks to the solution processing properties of quantum dots and their ability to integrate with silicon-based readout circuits on a single chip, infrared detectors based on HgTe CQDs have shown great application prospects. However, facing the challenges of vertically stacked photovoltaic devices, such as barrier layer matching and film non-uniformity, most devices integrated with readout circuits still use a planar structure, which limits the efficiency of light absorption and the effective separation and collection of photo-generated carriers. Here, by synthesizing high-quality HgTe CQDs and precisely controlling the interface quality, we have successfully fabricated a photovoltaic detector based on HgTe and ZnO QDs. At a working temperature of 80 K, this detector achieved a low dark current of 5.23×10-9 A cm-2, a high rectification ratio, and satisfactory detection sensitivity. This work paves a new way for the vertical integration of HgTe CQDs on silicon-based readout circuits, demonstrating their great potential in the field of high-performance infrared detection.

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History
  • Received:March 04,2024
  • Revised:March 18,2024
  • Adopted:March 21,2024
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