基于锗薄膜速率调制沉积的红外滤光片性能提升方法
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1.复旦大学信息科学与工程学院;2.中国科学院上海技术物理研究所;3.重庆理工大学机械工程学院

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国家自然科学基金项目,国家重点研发计划,中国科学院青年创新促进会


A method for enhancing the performance of infrared filters based on rate-modulated deposition of germanium films
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1.School of Information Science and Engineering, Fudan University;2.Shanghai Institute of Technical Physics, Chinese Academy of Sciences;3.College of Mechanical Engineering, Chongqing University of Technology;4.Department of Optical Science and Engineering,and Shanghai Ultra-Precision Optical Manufacturing Engineering Center,Fudan University,No. 220,Handan Road,Yangpu District

Fund Project:

National Natural Science Foundation of China, National key Research and Development Program of China, Youth Innovation Promotion Association of the Chinese Academy of Sciences

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    摘要:

    本文系统研究了沉积速率对锗(Ge)薄膜微观结构、宽波段光学特性(1.0–13.0 μm)及应力特性的影响,并提出了一种基于Ge薄膜速率调制沉积的红外滤光片性能提升方法。结果表明,通过调控沉积速率可有效降低Ge薄膜在短波红外、长波红外波段的光学吸收。研究发现,随着沉积速率的提高,Ge薄膜保持非晶态结构。在光学常数表征方面,分别采用Cody-Lorentz模型和经典Lorentz振子模型精确计算了Ge薄膜在1.0–2.5 μm和2.5–13.0 μm波段的光学常数。随着沉积速率的提升,Ge薄膜折射率逐渐增大;在短波红外波段,Ge薄膜消光系数随沉积速率增加而上升,这是由于Urbach尾部展宽所致;而在长波红外波段,消光系数则随沉积速率增加而降低,主要归因于Ge-O键伸缩振动所导致的光学吸收强度在逐渐降低。此外,薄膜的拉伸应力随沉积速率升高而减小。最后,通过实例验证了所提出的基于Ge薄膜速率调制沉积提升红外滤光片性能方法的有效性。本文为Ge薄膜在高性能红外滤光片中的应用提供了理论依据和技术支撑。

    Abstract:

    This study systematically investigated the influence of deposition rate on the structure, broadband optical properties (1.0–13.0 μm), and stress characteristics of Germanium (Ge) films. Additionally, a method for enhancing the performance of infrared filters based on rate-modulated deposition of Ge films was proposed. The optical absorption of Ge films in the short-wave infrared (SWIR) and long-wave infrared (LWIR) bands can be effectively reduced by modulating the deposition rate. As the deposition rate increases, the Ge films maintain an amorphous structure. The optical constants of the films in the 1.0–2.5 μm and 2.5–13.0 μm bands were precisely determined using the Cody-Lorentz model and the classical Lorentz oscillator model, respectively. Notably, higher deposition rates result in a gradual increase in the refractive index. The extinction coefficient increases with the deposition rate in the SWIR region, attributed to the widening of the Urbach tail, while it decreases in the LWIR region due to the reduced absorption caused by the Ge–O stretching mode. Additionally, the films exhibit a tensile stress that decreases with increasing deposition rate. Finally, the effectiveness of the proposed fabrication method for an infrared filter with Ge films deposited at an optimized rate was demonstrated through practical examples. This work provides theoretical and technical support for the application of Ge films in high-performance infrared filters.

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  • 收稿日期:2025-05-21
  • 最后修改日期:2025-06-11
  • 录用日期:2025-06-16
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