HgTe/ZnO量子点垂直堆叠异质结低暗电流光电探测器
作者:
作者单位:

1.中国科学院上海技术物理研究所 红外物理国家重点实验室,上海200083;2.中国科学院大学,北京100049;3.复旦大学 芯片与系统前沿技术研究院,上海 200438;4.昆明物理研究所,云南 昆明 650223

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O475

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A HgTe/ZnO quantum dots vertically stacked heterojunction low dark current photodetector
Author:
Affiliation:

1.State Key Laboratory of Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, Shanghai 200083, China;2.University of Chinese Academy of Sciences, Beijing 100049, China;3.Frontier Institute of Chip and System, Institute of Optoelectronics, Shanghai Frontier Base of Intelligent Optoelectronics and Perception, Fudan University, Shanghai 200438, China;4.Kunming Institute of Physics, Kunming 650223, China

Fund Project:

This work is supported by National key research and development program in the 14th five year plan (2021YFA1200700), Strategic Priority Research Program of the Chinese Academy of Sciences (XDB0580000), Natural Science Foundation of China (62025405, 62104235, 62105348).

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    摘要:

    胶体量子点(CQDs)受量子限域效应的影响,其带隙具有可调谐的特性,因此该类材料能够覆盖更宽的红外光谱范围,为突破传统红外探测器的技术路线提供了一种高成本效益的替代方案。近年来,得益于量子点的溶液加工特性以及其与硅基读出电路的单芯片集成能力,基于碲化汞胶体量子点的红外探测器展现出极大的应用前景。然而,面对垂直堆叠光伏器件的挑战,如阻挡层的匹配和薄膜非均匀性等问题,当前大部分与读出电路集成的器件仍采用平面结结构,限制了光吸收效率以及光生载流子的有效拆分和收集。在这里,我们通过合成高质量碲化汞量子点及精准控制界面质量,成功制备了基于HgTe和ZnO量子点材料的光伏型探测器。该探测器在80 K的工作温度下,实现了低至5.23×10-9 A cm-2的暗电流水平和较高的整流比,以及满意的探测灵敏度。这项工作为碲化汞量子点在硅基读出电路上的垂直集成开辟了新途径,展示了其在高性能红外探测领域的巨大潜力。

    Abstract:

    Colloidal quantum dots (CQDs) are affected by the quantum confinement effect, which makes their bandgap tunable. This characteristic allows these materials to cover a broader infrared spectrum, providing a cost-effective alternative to traditional infrared detector technology. Recently, thanks to the solution processing properties of quantum dots and their ability to integrate with silicon-based readout circuits on a single chip, infrared detectors based on HgTe CQDs have shown great application prospects. However, facing the challenges of vertically stacked photovoltaic devices, such as barrier layer matching and film non-uniformity, most devices integrated with readout circuits still use a planar structure, which limits the efficiency of light absorption and the effective separation and collection of photo-generated carriers. Here, by synthesizing high-quality HgTe CQDs and precisely controlling the interface quality, we have successfully fabricated a photovoltaic detector based on HgTe and ZnO QDs. At a working temperature of 80 K, this detector achieved a low dark current of 5.23×10-9 A cm-2, a high rectification ratio, and satisfactory detection sensitivity. This work paves a new way for the vertical integration of HgTe CQDs on silicon-based readout circuits, demonstrating their great potential in the field of high-performance infrared detection.

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黄新宁,姜腾腾,狄云翔,谢茂彬,郭天乐,刘晶晶,吴斌民,施静梅,秦强,邓功荣,陈艳,林铁,沈宏,孟祥建,王旭东,褚君浩,葛军,王建禄. HgTe/ZnO量子点垂直堆叠异质结低暗电流光电探测器[J].红外与毫米波学报,2025,44(1):33~39]. HUANG Xin-Ning, JIANG Teng-Teng, DI Yun-Xiang, XIE Mao-Bin, GUO Tian-Le, LIU Jing-Jing, WU Bin-Min, SHI Jing-Mei, QIN Qiang, DENG Gong-Rong, CHEN Yan, LIN Tie, SHEN Hong, MENG Xiang-Jian, WANG Xu-Dong, CHU Jun-Hao, GE Jun, WANG Jian-Lu. A HgTe/ZnO quantum dots vertically stacked heterojunction low dark current photodetector[J]. J. Infrared Millim. Waves,2025,44(1):33~39.]

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  • 收稿日期:2024-03-04
  • 最后修改日期:2024-10-03
  • 录用日期:2024-03-21
  • 在线发布日期: 2024-11-08
  • 出版日期: 2025-02-25
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