非平衡态电子测量:从超快动力学到稳态能量流红外被动近场成像
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中国科学院上海技术物理研究所

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国家重点研发计划青年科学家项目(2024YFA1410800);国家自然科学基金面上项目(62375277);中国科学院科研仪器研制项目(PTYQ2026YZ0019)


Probing Non-Equilibrium Electrons: From Ultrafast Dynamics to Passive Infrared Near-Field Imaging of Energy Flow at Steady-State
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Shanghai Institute of Technical Physics,Chinese Academy of Sciences

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    摘要:

    非平衡态电子过程广泛存在于半导体器件、量子相干体系、光电转换和微纳热管理等重要研究领域,是决定器件性能和能量转换效率的关键物理过程。长期以来,非平衡态电子测量常与超快时间分辨技术紧密联系,飞秒、皮秒乃至阿秒实验为电子弛豫、电子-声子耦合、光生载流子动力学和光诱导相变等问题提供了重要实验窗口。然而,真实工作器件中的电子系统并不总是表现为一次外部激发后的瞬态弛豫,而更多处于持续偏压、电流、光照或温差驱动下的稳态非平衡状态。此时,核心问题不只是电子如何随时间恢复平衡,而是电子如何在器件内部获得能量、携带能量并最终释放能量。本文首先从一般开放系统的宏观收支关系出发,区分平衡态、瞬态非平衡态和稳态非平衡态;随后概述典型超快电子动力学测量方法及其适用边界;再进一步从端口输运测量、高空间分辨纳米成像和非平衡电子能量转移三个层次,讨论工作器件中稳态非平衡态电子测量的价值与现有研究局限性。在此基础上,本文讨论了扫描噪声显微镜(Scanning Noise Microscope, SNoiM)等被动式红外近场成像方法的意义。SNoiM利用样品自身热涨落或非平衡电流涨落产生的电磁倏逝场,通过金属纳米探针将局域近场信号散射到远场并由高灵敏红外探测器读取,从而在纳米尺度上对工作器件中的热电子涨落和非平衡态电子能量分布进行实空间成像。本文指出,非平衡态电子测量在沿着更高时间分辨和更高空间分辨方向发展的同时,也需面向真实稳态工作条件,建立能够直接观测器件内部电子能量输运与耗散路径的红外近场超分辨测量新范式。

    Abstract:

    Non-equilibrium electronic processes are widespread in semiconductor devices, coherent quantum systems, optoelectronic conversion devices, and micro/nano thermal management. They are key physical processes that determine device performance and energy conversion efficiency. For a long time, non-equilibrium electron measurements have been closely linked to ultrafast time-resolved techniques. Femtosecond, picosecond, and even attosecond experiments have provided important experimental windows for problems such as electron relaxation, electron-phonon coupling, photogenerated carrier dynamics, and photoinduced phase transitions. However, electronic systems in real-world devices do not always exhibit transient relaxation after a single external excitation, but rather are more often in a steady-state non-equilibrium state driven by continuous bias, current, illumination, or temperature differences. In this case, the core issue is not just how electrons recover equilibrium over time, but how they acquire, carry, and ultimately release energy within the device. This paper first distinguishes between equilibrium, transient non-equilibrium, and steady-state non-equilibrium states based on the macroscopic budgetary relationships of general open systems. Then, it outlines typical ultrafast electron dynamics measurement methods and their applicable boundaries. Furthermore, it discusses the value and limitations of steady-state non-equilibrium electron measurements in working devices from three levels: port transport measurement, high spatial resolution nanoimaging, and non-equilibrium electron energy transfer. Building upon this foundation, this paper discusses the significance of passive infrared near-field imaging methods such as scanning noise microscope (SNoiM). SNoiM utilizes the evanescent electromagnetic field generated by thermal fluctuations or non-equilibrium current fluctuations in the sample. A metal nanoprobe scatters the local near-field signal to the far field, which is then read out by a highly sensitive detector, thereby imaging the hot electron fluctuations and non-equilibrium electron energy distribution in the working device at the nanoscale. This paper points out that while non-equilibrium electron measurement is developing towards higher temporal and spatial resolutions, it also needs to address real steady-state operating conditions and establish a new paradigm of infrared near-field super-resolution measurement that can directly observe the electron energy transport and dissipation paths inside the device.

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翁钱春.非平衡态电子测量:从超快动力学到稳态能量流红外被动近场成像[J].红外,2026,47(3):1-17.

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  • 收稿日期:2026-03-17
  • 最后修改日期:2026-03-19
  • 录用日期:2026-03-22
  • 在线发布日期: 2026-03-25
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