基于二维相关分析的ZnS材料声子交互作用
Received:April 17, 2017  Revised:May 12, 2017  点此下载全文
引用本文:刘华松,杨 霄,刘丹丹,李士达,季一勤,张锋,陈德应.基于二维相关分析的ZnS材料声子交互作用[J].Journal of Infrared and Millimeter Waves,2017,36(5):606~611
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Author NameAffiliationE-mail
LIU Hua-Song Tianjin Key Laboratory of Optical Thin Film,Tianjin Jinhang Technical Physics Institute,HIWING Technology Academy of CASIC,Tianjin liuhuasong@hotmail.com 
YANG Xiao Tianjin Key Laboratory of Optical Thin Film,Tianjin Jinhang Technical Physics Institute,HIWING Technology Academy of CASIC,Tianjin  
LIU Dan-Dan Tianjin Key Laboratory of Optical Thin Film,Tianjin Jinhang Technical Physics Institute,HIWING Technology Academy of CASIC,Tianjin  
LI Shi-Da Tianjin Key Laboratory of Optical Thin Film,Tianjin Jinhang Technical Physics Institute,HIWING Technology Academy of CASIC,Tianjin  
JI Yi-Qin Tianjin Key Laboratory of Optical Thin Film,Tianjin Jinhang Technical Physics Institute,HIWING Technology Academy of CASIC,Tianjin ji_yiqin@yahoo.com 
ZHANG Feng Tianjin Key Laboratory of Optical Thin Film,Tianjin Jinhang Technical Physics Institute,HIWING Technology Academy of CASIC,Tianjin  
CHEN De-Ying Harbin Institute of Technology  
基金项目:国家自然科学(61405145)、天津市自然科学重点基金(15JCZDJC31900)、中国博士后科学基金(2015T80115,2014M560104)
中文摘要:硫化锌材料是长波红外光学窗口材料优选材料之一.针对化学气相沉积(CVD)和热压成形(HP)两种工艺制备的硫化锌材料, 研究了从室温到600℃的光谱透过率变化现象, 基于二维相关光谱分析技术, 获得了长波吸收区内的声子交互作用.研究结果表明: 在700~1250 cm-1的长波吸收波段, CVD ZnS的声子频率为横向振动模式下(TO)的三次谐波频率和纵向声学模式下(LA)的三次谐波频率;HP ZnS的声子频率分别为3TO、3LA和4LA, 并且在温度作用下的响应顺序依次为3LA、3TO和4LA.两种工艺制备的ZnS杂质振动吸收在温度作用下对2000~1250 cm-1范围内的光谱透过率产生影响, 出现不同程度的透过率增加现象, 由于两者含有杂质的区别, 在高温下CVD ZnS的透过率变化比HP ZnS较为显著.
中文关键词:CVD ZnS, HP ZnS, 声子, 二维相关分析
 
Multi-phonon interaction of ZnS material based on two-dimensional correlation analysis
Abstract:Zinc sulfide material is one of the important materials for infrared optical window in the long wavelength region. In this paper, the change of the spectral transmittance from room temperature to 600℃ was studied for the zinc sulfide materials prepared by chemical vapor deposition (CVD) and hot pressing (HP). Based on the two-dimensional correlation spectrum analysis technique, the interaction of the phonons in the long wave absorption region was obtained. In the long wave absorption band from 700 cm-1 to 1 250 cm-1, the phonon frequencies of CVD ZnS is the third harmonic frequencies in the transverse vibration mode (TO) and the third harmonic frequency in the longitudinal acoustic mode (LA). The phonon frequencies of HP ZnS are 3TO, 3LA and 4LA, and the response under temperature is 3LA, 3TO and 4LA in proper order. The vibration absorption of ZnS impurity prepared by the two techniques has an effect on the spectral transmittance in the range from 1250 cm-1 to 2000 cm-1 under the action of temperature, and the increase of the transmittance in different degrees occurs. Because of the difference of impurities, the transmittance of CVD ZnS is more significant than that of HP ZnS at high temperature environment.
keywords:CVD  ZnS, HP  ZnS, phonon, two-dimensional  correlation analysis
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