介孔ZnO微球的制备及其在染料敏化太阳能电池中的应用
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National Natural Science Fundation of China by NSFC(20704042, and 60225004), the Shanghai City Committee of Science and Technology(06XD14020,07JC14058 and 0752nm016), Shanghai Pujiang Talent Plan(07pj14095),the Knowledge Innovation Program of Chinese Academy and Sciences(KSCX2-YW-G-042) and National Basic Research Program of China(2010CB933700)


PREPARATION OF MESOPOROUS ZnO MICROSPHERES AND THEIR APPLICATION IN DYE-SENSITIZED SOLAR CELLS
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    摘要:

    制备了一种新型的染料敏化太阳电池的光阳极,该电极由溶剂合成的具有高比表面积和良好光散射特性的ZnO介孔微球组成。采用X射线衍射、扫描电子显微镜、能谱仪及N2吸附脱附等手段,分析了介孔ZnO微球的结构和形貌。所得介孔微球尺寸在亚微米范围,比表面积约为50m2.g-1。将ZnO介孔微球成功应用到染料敏化太阳电池中,当光阳极为3μm时,组成的原型器件的短路电流密度约为4.5mA.cm-2,开路电压约为602mV,转换效率可达1.28%。研究结果表明,ZnO介孔微球是一种优异的染料敏化太阳电池的光阳极材料。

    Abstract:

    A novel ZnO photoanode with high specific surface area and good light scattering ability was fabricated for dyesensitized solar cells(DSSCs). The photoanode comprised of mesoporous ZnO microspheres which were prepared by a solvothermal process. The structures and morphologies of ZnO microspheres were measured and confirmed by means of x-ray diffraction ( XRD), scanning electron microscopy ( SEM ), energy dispersive spectrum ( EDS ), and multi-point Brunauer- Emmett-Teller(BET) analysis. ZnO microspheres are in sub-micrometer scale and have BET specific surface area of - m^2·g^-1. Furthermore, a - 3μm thick photoanode made from ZnO microspheres resultes in a preliminary short-circuit current density( Jsc ) of - 4. 5mA · cm^-2 with an open-circuit voltage (Vooc) of -602mV and a conversion efficiency of 1.28% in DSSCs. All these suggest that mesoporous ZnO microspheres can be an alternative and feasible photoanode material for DSSCs. Key words: ZnO; mesoporous microsphere; dye-sensitized solar cells (DSSCs)

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陶俊超,孙艳,葛美英,陈鑫,戴宁.介孔ZnO微球的制备及其在染料敏化太阳能电池中的应用[J].红外与毫米波学报,2010,29(1):1~5]. TAO Jun-Chao, SUN Yan, GE Mei-Ying, CHEN Xin, DAI Ning. PREPARATION OF MESOPOROUS ZnO MICROSPHERES AND THEIR APPLICATION IN DYE-SENSITIZED SOLAR CELLS[J]. J. Infrared Millim. Waves,2010,29(1):1~5.]

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  • 收稿日期:2009-12-28
  • 最后修改日期:2009-12-28
  • 录用日期:2009-12-29
  • 在线发布日期: 2009-12-29
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