The improved transmission and mirror system for a 263 GHz DNP-NMR spectrometer has been designed and numerically simulated based on the geometric optics theory and the vector diffraction theory. The system includes two corrugated waveguides, a parabolic mirror and an angle-adjustable phase-correcting mirror. The simulation results show that a well-focused Gaussian-like output wave-beam with 99.90% scalar Gaussian mode content, 99.55% vector Gaussian mode content has been obtained. The direction of the output beam can be changed by only adjusting the angle of the phase-correcting mirror to match the DNP-NMR sample. The scalar Gaussian mode content is about 99.57%, and the vector Gaussian mode content is about 98.97% when the direction of the output beam changes in ± 15^o.